Sulfur tetrachloride

Sulfur tetrachloride
Identifiers
CAS number 13451-08-6
Jmol-3D images Image 1
Properties
Molecular formula SCl4
Molar mass 173.87
Appearance White powder
Melting point

-31°C

Boiling point

-20°C (decomposes)

Solubility in water soluble in water
Hazards
R-phrases R14, R34, R50
S-phrases (S1/2), S26, S45, S61
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Sulfur tetrachloride is an inorganic compound with chemical formula SCl4. It is an unstable pale yellow solid, decomposing to sulfur dichloride and chlorine at temperatures above 242K. It is obtained by treating sulfur dichlorides with chlorine at 193K:

\rm \ SCl_2 %2B Cl_2 \xrightarrow{193K} SCl_4

Its structure is uncertain. It is probably the salt SCl3+Cl-, since related salts are known.[1]

References

  1. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Oxford: Butterworth-Heinemann. ISBN 0080379419.